September/October 2008
CS Home

About Colored Stone

Advertising Information
Archived Articles and News
Classifieds

Inside the Industry - Links and Information

News & Updates
Products & Resources
Search Products and Dealers
Show Calendar

Search Colored-Stone.com:

January/February 2010
This month's issue

Contact Customer Service

Colored Stone Back Issues

Entrance Strategy

It isn't easy to force copper into feldspar. So when gemologist Robert James said copper diffusion was the real cause of red and green in Mexican feldspar sold as natural on TV, and made the official gem of the 2008 Beijing Olympics, no one took him seriously—until he started snapping pictures to prove his point

By David Federman, Editor-in-Chief, Colored Stone


Above: Four (4) of the Direct Shopping Channel's 2008 Beijing Olympic Andesine, with certificate numbers 1450, 1482, 2086, and 2089

Ever read Henrik Ibsen's "An Enemy of the People"? It's a 19th century play about a doctor who discovers that his town's central source of income, its famous health spa, has poisoned waters and must fight an establishment in denial to warn the world at large.

For the last few months, gemologist Robert James, president of the International School of Gemology in San Antonio, Texas, has found himself in a situation very similar to that of Ibsen's whistle-blower doctor. He has been charging that tons of feldspar sold on TV and the Internet as all-natural were, in reality, artificially colored by copper diffusion.


Above: Andesine under plain 30 magnification showing the Olympic logo. Photo courtesy ISG.

The same gem as the top photo, placed in the immersion cell, showing classic diffusion patterns. Photo courtesy ISG.
These allegations have pitted him against some of the world's leading gem labs which were sent this material to test for treatment and, finding none, issued reports saying it was natural. Sellers of this suspect feldspar brandished these lab reports as defense against James' accusations. Like Ibsen's doctor, James soon found himself a pariah.

And no wonder. A lot was riding on the all-natural status of this feldspar. [Feldspar is a complex gem group divided into two branches: orthoclase and plagioclase. Of interest here is the second group which is arbitrarily divided into six parts, based on the increasing ratio of calcium to sodium: albite, oligoclase, andesine, labradorite, bytownite and anorthite. TV feldspar was sold as both andesine and andesine-labradorite. From this point on, we will refer to the feldspar in question as "andesine," even though some gemologists familiar with this material insist it should be called "labradorite."]

First, millions of dollars worth of it were being sold on major shop-at-home TV networks. Second, this andesine had been adopted as the official gem of the 2008 Beijing Olympics. If the color was artificial, the ensuing scandal would be global in scope.

Determined to make his case, James disseminated incriminating photographs via the Internet that left those who saw them little choice but to entertain the thought that maybe TV andesine owed its color to some sort of gimmickry after all. In early May, these caught-in-the-act photographs convinced Colored Stone, which had long harbored suspicions of its own about this feldspar, to publish an article sympathetic to James's findings on its Web site.

Surprisingly, the magazine received only one letter critical of James' science. The remaining correspondence was overwhelmingly supportive. We encouraged James to continue his research.

In June, James decided to write a show-all/tell-all report on TV and Olympic Games andesine that detailed his research methodology and findings. When he offered Colored Stone exclusive first publication rights, we jumped at the opportunity because we felt pretty sure James would supply us with gemological confirmation of our own suspicions.

This is when things went wrong—or was it right? You be the judge.

From Goof to Grace
Believers in a world where everything happens by design and predestination may find the next part of the Robert James saga of great interest. Because of previous delays in Internet publishing, Colored Stone made the premature decision to convert James' report into Web-ready text. We should have waited until after it had been finalized. But, quite frankly, we wanted to be able to go 'live' with the story as quickly as possible.

On July 22, a Web technician accidentally sent the as-yet unedited report to every subscriber on Colored Stone's opt-in email list. After calling James to notify him that his report had been unintentionally released, we published a terse disclaimer the next day, explaining 1) that the report had been released prematurely and 2) that Mr. James' views were not necessarily those of the company. The disclaimer wasn't meant, as some subscribers wrote, to be a retraction. It was straightforward boilerplate meant to admit we goofed.

Keep in mind the following: Colored Stone had lobbed a live grenade into the middle of the market it covers, for the report argued and, to us anyway, made a convincing case for what many in the trade already feared: that TV and Internet red and green andesine sold as Asian in origin and all-natural in color was neither. So what was it?

The View from Malvern
I need to digress here for a moment. Readers must understand the parallel evidence-gathering processes that persuaded Colored Stone to report James' findings in May. Before we even knew that James was stirring up a hornets' nest, we already suspected a potential scandal. Here's what we had learned long before we knew of his sleuthing.

For starters, we had received reliable tips in 2007 that in all likelihood the TV andesine was not as purported, from the Congo or even Tibet and Mongolia. Our sources—including both a geologist who had studied the material and a dealer who had bought large quantities of it—were willing to bet the material was Mexican. Why?

First, Mexico was the only known country with a deposit of transparent feldspar capable of supplying enough material for sustained large-scale TV, Internet and Olympics marketing campaigns. Except for Oregon, there was no other known significant source of the kind of material needed for such gargantuan commercial efforts.

Second, the very nature of the Mexican material convinced us treatment was required if it was to be sold in red and green varieties. For those not familiar with Mexican feldspar, it is homogeneously yellow—with nary a trace of red or green. If this feldspar was to be sold as red or green andesine, the color would have to be induced. How?

This is where things got complicated. Experts versed in treatment who tried to induce red and green in yellow feldspar told us they had failed in their attempts. So while they shared our suspicions, they could not confirm them. But just because they failed didn't mean others hadn't succeeded. Our suspicions were not allayed.

Now let's skip to Tucson 2008 where I conducted a seminar on current gemological issues. There renowned treatment expert Ted Themelis told the audience that Thailand's master gem-color processors had developed a means to diffuse heavy elements into gems to induce major improvements in stone appearance. This method was a refinement of the light-element beryllium diffusion method used to convert Madagascar sapphires into "new-find" padparadscha around 2000. True, copper is a transitional element and not "heavy" in the sense Themelis meant. Nevertheless, I felt I had grounds to once again pursue my suspicions about TV andesine.

Those doubts only deepened when I learned that no one had ever been able to obtain certified Congolese, Tibetan or Mongolian andesine rough from which the new red and green "all-natural" andesine was being cut. I began to wonder if the "new-find" market mythology that surrounded TV andesine wasn't simply a variation on the new-find mythology used to explain the sudden profusion of fake-color padparadscha a few years earlier. Was the new find simply a new furnace used to artificially color gems?

Shortly after my skepticism peaked, Colored Stone's and Robert James' paths crossed.

The View from San Antonio


Above: what appears to be a lightly included red andesine. Notice the dark area in the center left.

The same gem as the top photo, placed in the immersion cell.

Zooming in on the stone to 30x magnification. The red diffusion filler material still intact, and still showing the artificial red color is imparted to this feldspar.

The same stone, out of the immersion cell, under 60x magnification.

The same stone under 90x magnification.
After Tucson, I couldn't shake my suspicion that a derivative Far East "bulk diffusion" technology was responsible for the color in TV andesine. If I was right, treaters were forcing copper into stones through surface-breaking cracks at near-melting point temperatures for prolonged periods to produce rare reds and greens. According to one source, a buyer at a shop-at-home TV network, a Japanese observer of the process reported it consisted of three 30-day high-heat and copper-diffusion cycles.

This is when I learned James had been leaking out photographic evidence confirming the same suspicions via two Web sites—www.yourgemologist.com and www.schoolofgemology.com. As purchasers of this now-suspect andesine discovered James' photos and findings, they sent him stones for scrutiny. Convinced by immersion cell testing that stones were diffusion-treated, James broke several stones that he bought and tested them using a Raman microscope. His suspicions solidified into certainties. Let's follow James' trail of evidence-gathering.

By the time James began openly expressing his doubts about the all-natural status of TV and Olympics andesine, some sellers were admitting that stones were treated—but purely by heating. That didn't make sense. Convinced TV andesine was Mexican in origin, James knew it to be strong in iron and deficient in the coloring agent of copper needed to produce red and green colors. So what good would mere heating do? James set out to find if stones had been altered using a combination of heat and copper diffusion.

After collecting more than 100 specimen stones direct from TV and Internet sellers, James raised enough money to purchase a Raman microscope for fine-tuned chemical analyses and spectra. Comparing his specimens to known samples of Mexican material, he found all were, in his words, "virtually identical." Poof! There went the validity of claims that the material was from Africa or Asia.

Next, James ran immersion tests of the material—including four stones sold as "Olympic Andesine," the official gemstone of the 2008 Beijing Olympics. All showed green cores and red rims. "What are the chances of this occurring in every andesine I tested?" James asked himself. The most likely way that there could be such consistency of stone interiors, he theorized, was if the red resulted from copper diffusion.

James went back to his microscope and examined stones for any tell-tale internal similarities. He found twinning, also called "lamella," but which he nicknamed "ribbons." What, he wanted to know, caused this internal phenomenon?

The Shots Seen Round the World

"Ribbons" are tiny tubular fissures that run through feldspar, often breaking the surface. If stones were subject to copper diffusion, James felt it only logical that some would show filler material in these cracks. Suspecting that this filler would be most evident in lower-quality stones with numerous filled fissures that had escaped notice by sellers, James went on the Internet and started bidding for inexpensive auction goods.

Sure enough, he found filler material crammed into the tiny tubular openings of these "liquidation" stones. His photos of these filler-caked cracks were the centerpiece of the report submitted to Colored Stone in late July and accidentally leaked to email subscribers. To his credit, James sent the report with these dramatic photomicrographs to leading establishment gemologists for their reaction. One of them, Lore Kiefert, head of the American Gem Trade Association's Gem Trade Laboratory, admitted they indicate the presence of some unidentified but suspicious material that she had not previously observed in feldspar. She wants James to submit actual samples of the material he studied to her for further study.

Joel Arem, well-known gemologist and author of the highly-praised "Color Encyclopedia of Gemstones," was more unequivocal. In a statement sent to Colored Stone, he wrote as follows: "I have seen the report by Robert James on "Olympic andesine" and other bits of his research data. As long ago as 2003 I had information that led me to believe that the huge volume of red/blue-green "andesine" coming out of China was artificially color-enhanced. I already knew the material was labradorite and not andesine, because I had tested it myself. If the sellers were mislabeling the very species, what other mischief was afoot? I applaud James' thorough approach to this issue and agree with his results. I do still remain open to information proving the existence of small quantities of natural red labradorite from Asia."

Other gemologists like Kiefert also hold out hope for a small Asian find of all-natural material which was the source of stones they tested and found kosher. For now, however, the onus of proof that such material has been found in any quantity whatsoever remains on those who sold it—not those who questioned its legitimacy.


Ribbons reaching the surface of the rough crystal.

ISG testing found this ribbon at the surface not only of this faceted "andesine labradorite" but also of the rough crystal during the diffusion treatment.

The above photo is an andesine specimen under higher magification -- many of the ribbon lamella showing how the diffusion filler material has filled a significant section of the ribbon.

Another example of a ribbon that has been totally distended by the filler material, which is showing a white powder that has filled this ribbon from one end of the stone to the other.

In the Aftermath
Once James' report was circulated around the world, its impact was immediate and dramatic. Of course, it helped that GIA seemed to be concurring with James' conclusions. Days after our release of his findings, we received the Summer 2008 issue of Gems & Gemology containing a brief report (pages 166-7) on tests of a single 1.30-carat "red andesine" from China by four French gemologists. Their photomicrographs of the stone also showed what they described as suspicious "red color concentrations around surface-reaching channels." In other words, they saw signs of treatment.

Next, the influential Asian Institute of Gemological Studies posted James' report exactly as it appeared in our dispatch on their Web site. What's more, the Gemmological Association of New Zealand sent a laudatory note to Robert James about his study and asked for permission to reprint it in their quarterly.

Suddenly, it seemed as if the gemological world was doing an about-face and accepting the reality of artificially-colored red andesine.

That's when former merchandisers of this material started to admit that it was, indeed, treated. Thai Gems, a major Internet seller of red andesine, reclassified the material as colored by "bulk diffusion Fe/Cu."

James was being vindicated.

What's Next?
The TV andesine scandal is particularly alarming because it suggests a new ubiquity of high-tech diffusion treatment for which detection is difficult. James is worried that this process has been applied to other copper-bearing and copper-colored gemstones.

You can guess which one he has in mind: cuprian elbaite now being sold worldwide as "Paraiba" tourmaline. James is fearful that many African tourmalines have been diffused with copper to legitimize their classification as "Paraiba."

His preliminary tests, he says, would seem to confirm his fears. As you can see from the following photographs showing color cores and rims eerily similar to those found in copper-diffused andesine, Asia's alchemists may be working the same kind of false wonders with tourmaline that they have with feldspar.


A green paraiba in an immersion cell.

A filled fissure in a blue paraiba.

IS IT BYTOWNITE, ANDESINE, OR LABRADORITE?
IT REALLY DOESN'T MATTER

Plagioclase feldspars, as a group, are probably the most abundant minerals on earth and are essential constituents of nearly all igneous rocks. This group is a "solid solution series", with sodium aluminum silicate (albite) at one end, and anorthite (calcium aluminum silicate) at the other.

The exact ratio of sodium to calcium in any given plagioclase feldspar crystal varies according to the chemistry and growth conditions when it formed. The series was long-ago divided by mineralogists, for convenience, into 6 distinct species. This division is basically arbitrary - there could have been 4 species designated, or 10, or any other number. The "definition" of one of these feldspars is nothing more than the range of Na/Ca ratios that it represents. The species names are therefore irrelevant. All that matters is the ratio of sodium to calcium in the structure.

In the middle of the series (from 30% Ca to 90% Ca) there are three "labeled" minerals: andesine, labradorite and bytownite. Optical properties vary (approximately) linearly with composition. It is ridiculous to argue whether a given feldspar crystal is labradorite or bytownite, for example, when the only physical 'distinction' between these two minerals can be as little as 1-2% sodium versus calcium in the structure!! Property variations this size can even occur within a single zoned plagioclase crystal!

Since all these feldspars have the same structure and crystallized from a magma, their amenability to diffusion would not be significantly different. We may therefore conclude that the species "labels" applied by gem dealers to these feldspars have no bearing whatever on the possibility of treatment and the fundamental issue of disclosure.

--Joel Arem


This was also sent out to our Colored Stone GemMail newsletter subscribers. Want to receive the latest up-to-date information on the gemstone industry? Sign up for our free Colored Stone GemMail newsletter.

 

 

____________________
Colored Stone Home

e-mail the editors of Colored Stone | About Colored Stone | Sign up for the FREE Colored Stone GemMail newsletter

subscription customer service | Colored Stone Back Issues

This site and all of its contents are copyright Colored Stone and Interweave unless otherwise noted.
All articles, photographs, graphics, logos, and trade show floorplans are owned by Colored Stone and may not be reproduced in any form,
in print or in electronic media, without the express written permission of the publisher. Violators will be subject to legal action.


Copyright 2010. Colored Stone/Interweave. All rights reserved.